橋川 祥史

最終更新日時: 2019/07/10 10:23:14

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氏名(漢字/フリガナ/アルファベット表記)
橋川 祥史/ハシカワ ヨシフミ/Hashikawa, Yoshifumi
所属部署・職名(部局/所属/講座等/職名)
化学研究所/物質創製化学研究系/助教
協力講座
部局 所属 講座等 職名
工学研究科 物質エネルギー化学専攻 物質変換科学講座 助教
取得学位
学位名(日本語) 学位名(英語) 大学(日本語) 大学(英語) 取得区分
修士(工学) 京都大学
博士(工学) 京都大学
ORCID ID
https://orcid.org/0000-0001-7834-9593
researchmap URL
https://researchmap.jp/7000019583
研究テーマ
(日本語)
3次元π共役系の創出
(英語)
Creation of Three-Dimensional Pi-Conjugated Systems
研究概要
(日本語)
sp2炭素骨格に覆われた球状炭素空間に単一分子を取り出し,その性質ならびに動的挙動を緩和時間測定・理論化学計算によって明らかにしている.また,遷移金属触媒を用いた開口フラーレン誘導体の位置選択的構造修飾法の開発を行なっている.
(英語)
By utilizing relaxation time measurements as well as theoretical calculations, we attempt to elucidate the anomalous nature and dynamic behavior of a single molecule geometrically isolated inside a spherical carbon nanocavity. We also develop the regiocontrolled modification for the skeletons of cage-opened fullerene derivatives.
研究分野(キーワード)
キーワード(日本語) キーワード(英語)
構造有機化学 Structural Organic Chemistry
核磁気共鳴 Nuclear Magnetic Resonance
フラーレン Fullerene
論文
著者 著者(日本語) 著者(英語) タイトル タイトル(日本語) タイトル(英語) 書誌情報等 書誌情報等(日本語) 書誌情報等(英語) 出版年月 査読の有無 記述言語 掲載種別 公開
Hal Suzuki, Motohiro Nakano, Yoshifumi Hashikawa, Yasujiro Murata Hal Suzuki, Motohiro Nakano, Yoshifumi Hashikawa, Yasujiro Murata Hal Suzuki, Motohiro Nakano, Yoshifumi Hashikawa, Yasujiro Murata Rotational Motion and Nuclear Spin Interconversion of H <inf>2</inf> O Encapsulated in C <inf>60</inf> Appearing in the Low-Temperature Heat Capacity Rotational Motion and Nuclear Spin Interconversion of H <inf>2</inf> O Encapsulated in C <inf>60</inf> Appearing in the Low-Temperature Heat Capacity Rotational Motion and Nuclear Spin Interconversion of H <inf>2</inf> O Encapsulated in C <inf>60</inf> Appearing in the Low-Temperature Heat Capacity Journal of Physical Chemistry Letters, 10, 1306-1311 Journal of Physical Chemistry Letters, 10, 1306-1311 Journal of Physical Chemistry Letters, 10, 1306-1311 2019/03/21 公開
Yoshifumi Hashikawa, Yasujiro Murata Yoshifumi Hashikawa, Yasujiro Murata Yoshifumi Hashikawa, Yasujiro Murata Probing the Regioselectivity with Encapsulated H <inf>2</inf> : Diels–Alder Reaction of an Open-Cage C <inf>60</inf> Derivative with Anthracene Probing the Regioselectivity with Encapsulated H <inf>2</inf> : Diels–Alder Reaction of an Open-Cage C <inf>60</inf> Derivative with Anthracene Probing the Regioselectivity with Encapsulated H <inf>2</inf> : Diels–Alder Reaction of an Open-Cage C <inf>60</inf> Derivative with Anthracene Chemistry - A European Journal, 25, 2482-2485 Chemistry - A European Journal, 25, 2482-2485 Chemistry - A European Journal, 25, 2482-2485 2019/02/18 公開
Shintaro Fujii, Haruna Cho, Yoshifumi Hashikawa, Tomoaki Nishino, Yasujiro Murata, Manabu Kiguchi Shintaro Fujii, Haruna Cho, Yoshifumi Hashikawa, Tomoaki Nishino, Yasujiro Murata, Manabu Kiguchi Shintaro Fujii, Haruna Cho, Yoshifumi Hashikawa, Tomoaki Nishino, Yasujiro Murata, Manabu Kiguchi Tuneable single-molecule electronic conductance of C<inf>60</inf> by encapsulation Tuneable single-molecule electronic conductance of C<inf>60</inf> by encapsulation Tuneable single-molecule electronic conductance of C<inf>60</inf> by encapsulation Physical Chemistry Chemical Physics, 21, 12606-12610 Physical Chemistry Chemical Physics, 21, 12606-12610 Physical Chemistry Chemical Physics, 21, 12606-12610 2019/01/01 公開
Yoshifumi Hashikawa, Yasujiro Murata Yoshifumi Hashikawa, Yasujiro Murata Yoshifumi Hashikawa, Yasujiro Murata Wavelength-Dependent Efficiency of Sequential Photooxygenation: C=C Bond Cleavage on Open-Cage C<inf>60</inf> Derivatives Wavelength-Dependent Efficiency of Sequential Photooxygenation: C=C Bond Cleavage on Open-Cage C<inf>60</inf> Derivatives Wavelength-Dependent Efficiency of Sequential Photooxygenation: C=C Bond Cleavage on Open-Cage C<inf>60</inf> Derivatives ChemPlusChem, 83, 1179-1183 ChemPlusChem, 83, 1179-1183 ChemPlusChem, 83, 1179-1183 2018/12/01 公開
Shota Hasegawa, Yoshifumi Hashikawa, Tatsuhisa Kato, Yasujiro Murata Shota Hasegawa, Yoshifumi Hashikawa, Tatsuhisa Kato, Yasujiro Murata Shota Hasegawa, Yoshifumi Hashikawa, Tatsuhisa Kato, Yasujiro Murata Construction of a Metal-Free Electron Spin System by Encapsulation of an NO Molecule Inside an Open-Cage Fullerene C<inf>60</inf> Derivative Construction of a Metal-Free Electron Spin System by Encapsulation of an NO Molecule Inside an Open-Cage Fullerene C<inf>60</inf> Derivative Construction of a Metal-Free Electron Spin System by Encapsulation of an NO Molecule Inside an Open-Cage Fullerene C<inf>60</inf> Derivative Angewandte Chemie - International Edition, 57, 12804-12808 Angewandte Chemie - International Edition, 57, 12804-12808 Angewandte Chemie - International Edition, 57, 12804-12808 2018/09/24 公開
Guo Zhu Zhu, Yuan Liu, Yoshifumi Hashikawa, Qian Fan Zhang, Yasujiro Murata, Lai Sheng Wang Guo Zhu Zhu, Yuan Liu, Yoshifumi Hashikawa, Qian Fan Zhang, Yasujiro Murata, Lai Sheng Wang Guo Zhu Zhu, Yuan Liu, Yoshifumi Hashikawa, Qian Fan Zhang, Yasujiro Murata, Lai Sheng Wang Probing the interaction between the encapsulated water molecule and the fullerene cages in H <inf>2</inf> O@C <inf>60</inf><sup>-</sup> and H <inf>2</inf> O@C <inf>59</inf> N <sup>-</sup> Probing the interaction between the encapsulated water molecule and the fullerene cages in H <inf>2</inf> O@C <inf>60</inf><sup>-</sup> and H <inf>2</inf> O@C <inf>59</inf> N <sup>-</sup> Probing the interaction between the encapsulated water molecule and the fullerene cages in H <inf>2</inf> O@C <inf>60</inf><sup>-</sup> and H <inf>2</inf> O@C <inf>59</inf> N <sup>-</sup> Chemical Science, 9, 5666-5671 Chemical Science, 9, 5666-5671 Chemical Science, 9, 5666-5671 2018/01/01 公開
Yoshifumi Hashikawa, Shota Hasegawa, Yasujiro Murata Yoshifumi Hashikawa, Shota Hasegawa, Yasujiro Murata Yoshifumi Hashikawa, Shota Hasegawa, Yasujiro Murata A single: But hydrogen-bonded water molecule confined in an anisotropic subnanospace A single: But hydrogen-bonded water molecule confined in an anisotropic subnanospace A single: But hydrogen-bonded water molecule confined in an anisotropic subnanospace Chemical Communications, 54, 13686-13689 Chemical Communications, 54, 13686-13689 Chemical Communications, 54, 13686-13689 2018/01/01 公開
Hashikawa Yoshifumi, Yasui Hidefumi, Kurotobi Kei, Murata Yasujiro Hashikawa Yoshifumi, Yasui Hidefumi, Kurotobi Kei, Murata Yasujiro Hashikawa Yoshifumi, Yasui Hidefumi, Kurotobi Kei, Murata Yasujiro Synthesis and properties of open-cage fullerene C-60 derivatives: impact of the extended pi-conjugation Synthesis and properties of open-cage fullerene C-60 derivatives: impact of the extended pi-conjugation Synthesis and properties of open-cage fullerene C-60 derivatives: impact of the extended pi-conjugation Materials Chemistry Frontiers, 2, 2, 206-213 Materials Chemistry Frontiers, 2, 2, 206-213 Materials Chemistry Frontiers, 2, 2, 206-213 2018 公開
Hashikawa Yoshifumi, Murata Yasujiro Hashikawa Yoshifumi, Murata Yasujiro Hashikawa Yoshifumi, Murata Yasujiro Facile Access to Azafullerenyl Cation C59N+ and Specific Interaction with Entrapped Molecules Facile Access to Azafullerenyl Cation C59N+ and Specific Interaction with Entrapped Molecules Facile Access to Azafullerenyl Cation C59N+ and Specific Interaction with Entrapped Molecules Journal of the American Chemical Society, 139, 51, 18468-18471 Journal of the American Chemical Society, 139, 51, 18468-18471 Journal of the American Chemical Society, 139, 51, 18468-18471 2017 公開
Zhu Guo-Zhu, Hashikawa Yoshifumi, Liu Yuan, Zhang Qian-Fan, Cheung Ling Fung, Murata Yasujiro, Wang Lai-Sheng Zhu Guo-Zhu, Hashikawa Yoshifumi, Liu Yuan, Zhang Qian-Fan, Cheung Ling Fung, Murata Yasujiro, Wang Lai-Sheng Zhu Guo-Zhu, Hashikawa Yoshifumi, Liu Yuan, Zhang Qian-Fan, Cheung Ling Fung, Murata Yasujiro, Wang Lai-Sheng High-Resolution Photoelectron Imaging of Cryogenically-Cooled C59N- and (C59N)(2)(2-) Azafullerene Anions High-Resolution Photoelectron Imaging of Cryogenically-Cooled C59N- and (C59N)(2)(2-) Azafullerene Anions High-Resolution Photoelectron Imaging of Cryogenically-Cooled C59N- and (C59N)(2)(2-) Azafullerene Anions Journal of Physical Chemistry Letters, 8, 24, 6220-6225 Journal of Physical Chemistry Letters, 8, 24, 6220-6225 Journal of Physical Chemistry Letters, 8, 24, 6220-6225 2017 公開
Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Orientation of a Water Molecule: Effects on Electronic Nature of the C59N Cage Orientation of a Water Molecule: Effects on Electronic Nature of the C59N Cage Orientation of a Water Molecule: Effects on Electronic Nature of the C59N Cage Journal of Organic Chemistry, 82, 8, 4465-4469 Journal of Organic Chemistry, 82, 8, 4465-4469 Journal of Organic Chemistry, 82, 8, 4465-4469 2017 公開
Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Palladium-Catalyzed Cyclization: Regioselectivity and Structure of Arene-Fused C-60 Derivatives Palladium-Catalyzed Cyclization: Regioselectivity and Structure of Arene-Fused C-60 Derivatives Palladium-Catalyzed Cyclization: Regioselectivity and Structure of Arene-Fused C-60 Derivatives Journal of the American Chemical Society, 139, 45, 16350-16358 Journal of the American Chemical Society, 139, 45, 16350-16358 Journal of the American Chemical Society, 139, 45, 16350-16358 2017 公開
Kaneko Satoshi, Hashikawa Yoshifumi, Fujii Shintaro, Murata Yasujiro, Kiguchi Manabu Kaneko Satoshi, Hashikawa Yoshifumi, Fujii Shintaro, Murata Yasujiro, Kiguchi Manabu Kaneko Satoshi, Hashikawa Yoshifumi, Fujii Shintaro, Murata Yasujiro, Kiguchi Manabu Single Molecular Junction Study on H2O@C-60:H2O is "Electrostatically Isolated" Single Molecular Junction Study on H2O@C-60:H2O is "Electrostatically Isolated" Single Molecular Junction Study on H2O@C-60:H2O is "Electrostatically Isolated" Chemphyschem, 18, 10, 1229-1233 Chemphyschem, 18, 10, 1229-1233 Chemphyschem, 18, 10, 1229-1233 2017 公開
Ozaki Masashi, Katsuki Yukie, Liu Jiewei, Handa Taketo, Nishikubo Ryosuke, Yakumaru Shinya, Hashikawa Yoshifiimi, Murata Yasujiro, Saito Takashi, Shimakawa Yuichi, Kanemitsu Yoshihiko, Saeki Akinori, Wakamiya Atsushi Ozaki Masashi, Katsuki Yukie, Liu Jiewei, Handa Taketo, Nishikubo Ryosuke, Yakumaru Shinya, Hashikawa Yoshifiimi, Murata Yasujiro, Saito Takashi, Shimakawa Yuichi, Kanemitsu Yoshihiko, Saeki Akinori, Wakamiya Atsushi Ozaki Masashi, Katsuki Yukie, Liu Jiewei, Handa Taketo, Nishikubo Ryosuke, Yakumaru Shinya, Hashikawa Yoshifiimi, Murata Yasujiro, Saito Takashi, Shimakawa Yuichi, Kanemitsu Yoshihiko, Saeki Akinori, Wakamiya Atsushi Solvent-Coordinated Tin Halide Complexes as Purified Precursors for Tin-Based Perovskites Solvent-Coordinated Tin Halide Complexes as Purified Precursors for Tin-Based Perovskites Solvent-Coordinated Tin Halide Complexes as Purified Precursors for Tin-Based Perovskites Acs Omega, 2, 10, 7016-7021 Acs Omega, 2, 10, 7016-7021 Acs Omega, 2, 10, 7016-7021 2017 公開
Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Structural modification of open-cage fullerene C-60 derivatives having a small molecule inside their cavities Structural modification of open-cage fullerene C-60 derivatives having a small molecule inside their cavities Structural modification of open-cage fullerene C-60 derivatives having a small molecule inside their cavities Canadian Journal of Chemistry, 95, 3, 320-328 Canadian Journal of Chemistry, 95, 3, 320-328 Canadian Journal of Chemistry, 95, 3, 320-328 2017 公開
Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Co(I)-Mediated Removal of Addends on the C-60 Cage and Formation of the Monovalent Cobalt Complex CpCo(CO)(eta(2)-C-60) Co(I)-Mediated Removal of Addends on the C-60 Cage and Formation of the Monovalent Cobalt Complex CpCo(CO)(eta(2)-C-60) Co(I)-Mediated Removal of Addends on the C-60 Cage and Formation of the Monovalent Cobalt Complex CpCo(CO)(eta(2)-C-60) Organic Letters, 18, 24, 6348-6351 Organic Letters, 18, 24, 6348-6351 Organic Letters, 18, 24, 6348-6351 2016 公開
Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Synthesis and Properties of Endohedral Aza[60]fullerenes: H2O@C59N and H-2@C59N as Their Dimers and Monomers Synthesis and Properties of Endohedral Aza[60]fullerenes: H2O@C59N and H-2@C59N as Their Dimers and Monomers Synthesis and Properties of Endohedral Aza[60]fullerenes: H2O@C59N and H-2@C59N as Their Dimers and Monomers Journal of the American Chemical Society, 138, 12, 4096-4104 Journal of the American Chemical Society, 138, 12, 4096-4104 Journal of the American Chemical Society, 138, 12, 4096-4104 2016 公開
Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Water Entrapped inside Fullerene Cages: A Potential Probe for Evaluation of Bond Polarization Water Entrapped inside Fullerene Cages: A Potential Probe for Evaluation of Bond Polarization Water Entrapped inside Fullerene Cages: A Potential Probe for Evaluation of Bond Polarization Angewandte Chemie-International Edition, 55, 42, 13109-13113 Angewandte Chemie-International Edition, 55, 42, 13109-13113 Angewandte Chemie-International Edition, 55, 42, 13109-13113 2016 公開
Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Hashikawa Yoshifumi, Murata Michihisa, Wakamiya Atsushi, Murata Yasujiro Synthesis of Open-Cage Ketolactam Derivatives of Fullerene C-60 Encapsulating a Hydrogen Molecule Synthesis of Open-Cage Ketolactam Derivatives of Fullerene C-60 Encapsulating a Hydrogen Molecule Synthesis of Open-Cage Ketolactam Derivatives of Fullerene C-60 Encapsulating a Hydrogen Molecule Organic Letters, 16, 11, 2970-2973 Organic Letters, 16, 11, 2970-2973 Organic Letters, 16, 11, 2970-2973 2014 公開

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タイトル言語:
書籍等出版物
著者 著者(日本語) 著者(英語) タイトル タイトル(日本語) タイトル(英語) 出版社 出版社(日本語) 出版社(英語) 出版年月 記述言語 担当区分 公開
村田 靖次郎,張 鋭,橋川 祥史 村田 靖次郎,張 鋭,橋川 祥史 Yoshifumi Hashikawa フラーレン誘導体・内包技術の最前線 フラーレン誘導体・内包技術の最前線 Cutting-edge Technology in Fullerene Derivatives and Endohedral Fullerenes シーエムシー出版 シーエムシー出版 2014/04 分担執筆 公開
タイトル言語:
外部資金:競争的資金・科学研究費補助金
種別 代表/分担 テーマ(日本語) テーマ(英語) 期間
研究活動スタート支援 代表 分子間相互作用に基づく球状π空間の物性制御 (平成29年度分) 2017/04/01〜2018/03/31
若手研究 代表 弱い相互作用を用いた3次元π共役分子のナノ構造制御と機能開拓 (平成30年度分) 2018/04/01〜2019/03/31
特別研究員奨励費 (DC1) 代表 新規ヘテロフラーレンの創製とゲスト分子の内包 2015/04/01〜2017/03/31
外部資金:競争的資金・科学研究費補助金以外
制度名 代表者名 研究課題(日本語) 研究課題(英語) 期間
平成29年度 京都大学若手研究者スタートアップ研究費 代表 分子間相互作用に基づく球状π空間の物性制御 2017/04/〜2017/09/
平成30年度 統合物質創製化学研究推進機構「融合創発研究」 代表 小分子導入にもとづくC60骨格への電子的効果の検証 2018/07/〜2019/03/
平成30年度 化学研究所らしい融合的・開拓的研究 分担 官能基の配列方向に由来するキラリティを有する開口フラーレン誘導体の触媒的光学分割 2018/04/〜2019/03/
担当科目
講義名(日本語) 講義名(英語) 開講期 学部/研究科 年度
物質エネルギー化学特論第三 Energy and Hydrocarbon Chemistry, Adv. III 前期 工学研究科 2018/04〜2019/03
物質エネルギー化学特論第四 Energy and Hydrocarbon Chemistry, Adv. IV 前期 工学研究科 2018/04〜2019/03
部局運営(役職等)
役職名 期間
化学研究所安全衛生委員会委員 2018/04/01〜2019/03/31