森﨑 一宏

Last Update: 2019/08/30 17:50:23

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Name(Kanji/Kana/Abecedarium Latinum)
森﨑 一宏/モリサキ カズヒロ/Morisaki, Kazuhiro
Primary Affiliation(Org1/Job title)
Institute for Chemical Research (ICR)/Assistant Professor
Affiliated programs (koza)
Org1 Job title
Graduate Schools Pharmaceutical Sciences Assistant Professor
Academic Degree
Field(Japanese) Field(English) University(Japanese) University(English) Method
修士（創薬科学） 九州大学
博士（創薬科学） 九州大学
ORCID ID
https://orcid.org/0000-0002-5692-4726
researchmap URL
https://researchmap.jp/7000023080
Research Topics
(Japanese)
現在以下の課題に取り組んでいる。 ・C-H官能基化反応における選択性制御および遠隔位認識 ・触媒的遠隔位不斉誘導 ・超分子の不斉合成 ・不斉記憶型反応による非天然アミノ酸含有ペプチドの効率的合成
(English)
Site-selective C-H bond functionalization via remote functionality recognition Remote asymmetric induction Asymmetric synthesis of topological chiral molecules Development of facile synthetic methods for unnatural amino acid-containing peptides via Memory Of Chirality
Fields of research (key words)
Key words(Japanese) Key words(English)
位置選択的反応、 C-H官能基化反応 Site-Selectivity, C-H functionalization
遠隔位不斉誘導 Remote Assymetric Induction
Published Papers
Author Author(Japanese) Author(English) Title Title(Japanese) Title(English) Bibliography Bibliography(Japanese) Bibliography(English) Publication date Refereed paper Language Publishing type Disclose
Yuta Kondo, Kazuhiro Morisaki, Yoshinobu Hirazawa, Hiroyuki Morimoto, and Takashi Ohshima Yuta Kondo, Kazuhiro Morisaki, Yoshinobu Hirazawa, Hiroyuki Morimoto, and Takashi Ohshima Yuta Kondo, Kazuhiro Morisaki, Yoshinobu Hirazawa, Hiroyuki Morimoto, and Takashi Ohshima A Convenient Preparation Method for Benzophenone Imine Catalyzed by Tetrabutylammonium Fluoride A Convenient Preparation Method for Benzophenone Imine Catalyzed by Tetrabutylammonium Fluoride A Convenient Preparation Method for Benzophenone Imine Catalyzed by Tetrabutylammonium Fluoride Organic Process Research & Development, 28, 00, 1718-1724 Organic Process Research & Development, 28, 00, 1718-1724 Organic Process Research & Development, 28, 00, 1718-1724 2019/07 Refereed English Disclose to all
Ryohei Yonesaki, Yuta Kondo, Walaa Akkad, Masanao Sawa, Kazuhiro Morisaki, Hiroyuki Morimoto, Takashi Ohshima Ryohei Yonesaki, Yuta Kondo, Walaa Akkad, Masanao Sawa, Kazuhiro Morisaki, Hiroyuki Morimoto, Takashi Ohshima Ryohei Yonesaki, Yuta Kondo, Walaa Akkad, Masanao Sawa, Kazuhiro Morisaki, Hiroyuki Morimoto, Takashi Ohshima 3-Mono-Substituted BINOL Phosphoric Acids as Effective Organocatalysts in Direct Enantioselective Friedel–Crafts-Type Alkylation of N-Unprotected α-Ketiminoester 3-Mono-Substituted BINOL Phosphoric Acids as Effective Organocatalysts in Direct Enantioselective Friedel–Crafts-Type Alkylation of N-Unprotected α-Ketiminoester 3-Mono-Substituted BINOL Phosphoric Acids as Effective Organocatalysts in Direct Enantioselective Friedel–Crafts-Type Alkylation of N-Unprotected α-Ketiminoester Chemistry - A European Journal, 24, 15211-15214 Chemistry - A European Journal, 24, 15211-15214 Chemistry - A European Journal, 24, 15211-15214 2018/10/12 Disclose to all
Kenta Arai, Yoshihiro Ueda, Kazuhiro Morisaki, Takumi Furuta, Takahiro Sasamori, Norihiro Tokitoh, Takeo Kawabata Kenta Arai, Yoshihiro Ueda, Kazuhiro Morisaki, Takumi Furuta, Takahiro Sasamori, Norihiro Tokitoh, Takeo Kawabata Kenta Arai, Yoshihiro Ueda, Kazuhiro Morisaki, Takumi Furuta, Takahiro Sasamori, Norihiro Tokitoh, Takeo Kawabata Intermolecular Chemo- and Regioselective Aromatic C-H Amination of Alkoxyarenes Promoted by Rhodium Nitrenoids Intermolecular Chemo- and Regioselective Aromatic C-H Amination of Alkoxyarenes Promoted by Rhodium Nitrenoids Intermolecular Chemo- and Regioselective Aromatic C-H Amination of Alkoxyarenes Promoted by Rhodium Nitrenoids Chemical Communications Chemical Communications Chemical Communications 2018 Refereed Disclose to all
Kazuhiro Morisaki, Hiroyuki Morimoto, Kazushi Mashima, Takashi Ohshima Kazuhiro Morisaki, Hiroyuki Morimoto, Kazushi Mashima, Takashi Ohshima Kazuhiro Morisaki, Hiroyuki Morimoto, Kazushi Mashima, Takashi Ohshima Development of Direct Enantioselective Alkynylation of α-Ketoester and α-Ketiminoesters Catalyzed by Phenylbis(oxazoline)Rh(III) Complexes Development of Direct Enantioselective Alkynylation of α-Ketoester and α-Ketiminoesters Catalyzed by Phenylbis(oxazoline)Rh(III) Complexes Development of Direct Enantioselective Alkynylation of α-Ketoester and α-Ketiminoesters Catalyzed by Phenylbis(oxazoline)Rh(III) Complexes Journal of Synthetic Organic Chemistry, Japan, 76, 3, 226 Journal of Synthetic Organic Chemistry, Japan, 76, 3, 226 Journal of Synthetic Organic Chemistry, Japan, 76, 3, 226 2018 Refereed Disclose to all
Masanao Sawa, Kazuhiro Morisaki, Yuta Kondo, Hiroyuki Morimoto, Takashi Ohshima Masanao Sawa, Kazuhiro Morisaki, Yuta Kondo, Hiroyuki Morimoto, Takashi Ohshima Masanao Sawa, Kazuhiro Morisaki, Yuta Kondo, Hiroyuki Morimoto, Takashi Ohshima Direct Access to N-Unprotected α- and/or β-Tetrasubstituted Amino Acid Esters via Direct Catalytic Mannich-Type Reactions Using N-Unprotected Trifluoromethyl Ketimines Direct Access to N-Unprotected α- and/or β-Tetrasubstituted Amino Acid Esters via Direct Catalytic Mannich-Type Reactions Using N-Unprotected Trifluoromethyl Ketimines Direct Access to N-Unprotected α- and/or β-Tetrasubstituted Amino Acid Esters via Direct Catalytic Mannich-Type Reactions Using N-Unprotected Trifluoromethyl Ketimines Chemistry - A European Journal Chemistry - A European Journal Chemistry - A European Journal 2017/09 Refereed Disclose to all
Kazuhiro Morisaki, Hiroyuki Morimoto, Takashi Ohshima Kazuhiro Morisaki, Hiroyuki Morimoto, Takashi Ohshima Kazuhiro Morisaki, Hiroyuki Morimoto, Takashi Ohshima Direct access to N-unprotected tetrasubstituted propargylamines via direct catalytic alkynylation of N-unprotected trifluoromethyl ketimines Direct access to N-unprotected tetrasubstituted propargylamines via direct catalytic alkynylation of N-unprotected trifluoromethyl ketimines Direct access to N-unprotected tetrasubstituted propargylamines via direct catalytic alkynylation of N-unprotected trifluoromethyl ketimines Chem. Commun., 53, 47, 6319 Chem. Commun., 53, 47, 6319 Chem. Commun., 53, 47, 6319 2017 Refereed Disclose to all
Morisaki K, Morimoto H, Mashima K, Ohshima T. Morisaki K, Morimoto H, Mashima K, Ohshima T. Morisaki K, Morimoto H, Mashima K, Ohshima T. Direct enantioselective alkynylation of α-ketoesters and α-ketiminoesters catalyzed by [bis(oxazoline)phenyl]rhodium(III) complexes Direct enantioselective alkynylation of α-ketoesters and α-ketiminoesters catalyzed by [bis(oxazoline)phenyl]rhodium(III) complexes Direct enantioselective alkynylation of α-ketoesters and α-ketiminoesters catalyzed by [bis(oxazoline)phenyl]rhodium(III) complexes Heterocycles, 95, 2, 637-661 Heterocycles, 95, 2, 637-661 Heterocycles, 95, 2, 637-661 2017 Refereed Disclose to all
Morisaki K, Kondo Y, Sawa M, Morimoto H, Ohshima T. Morisaki K, Kondo Y, Sawa M, Morimoto H, Ohshima T. Morisaki K, Kondo Y, Sawa M, Morimoto H, Ohshima T. Synthesis of 1-tetrasubstituted 2,2,2-trifluoroethylamine derivatives via palladium-catalyzed allylation of sp<sup>3</sup>C–H bonds Synthesis of 1-tetrasubstituted 2,2,2-trifluoroethylamine derivatives via palladium-catalyzed allylation of sp<sup>3</sup>C–H bonds Synthesis of 1-tetrasubstituted 2,2,2-trifluoroethylamine derivatives via palladium-catalyzed allylation of sp<sup>3</sup>C–H bonds Chemical and Pharmaceutical Bulletin, 65, 11, 1089-1092 Chemical and Pharmaceutical Bulletin, 65, 11, 1089-1092 Chemical and Pharmaceutical Bulletin, 65, 11, 1089-1092 2017 Refereed Disclose to all
Morisaki K, Sawa M, Yonesaki R, Morimoto H, Mashima K, Ohshima T. Morisaki K, Sawa M, Yonesaki R, Morimoto H, Mashima K, Ohshima T. Morisaki K, Sawa M, Yonesaki R, Morimoto H, Mashima K, Ohshima T. Mechanistic Studies and Expansion of the Substrate Scope of Direct Enantioselective Alkynylation of α-Ketiminoesters Catalyzed by Adaptable (Phebox)Rhodium(III) Complexes Mechanistic Studies and Expansion of the Substrate Scope of Direct Enantioselective Alkynylation of α-Ketiminoesters Catalyzed by Adaptable (Phebox)Rhodium(III) Complexes Mechanistic Studies and Expansion of the Substrate Scope of Direct Enantioselective Alkynylation of α-Ketiminoesters Catalyzed by Adaptable (Phebox)Rhodium(III) Complexes Journal of the American Chemical Society, 138, 19, 6194-6203 Journal of the American Chemical Society, 138, 19, 6194-6203 Journal of the American Chemical Society, 138, 19, 6194-6203 2016 Refereed Disclose to all
T. Ohshima, H. Morimoto, K. Morisaki T. Ohshima, H. Morimoto, K. Morisaki T. Ohshima, H. Morimoto, K. Morisaki Catalytic Asymmetric 1,2-Alkynylation☆ Catalytic Asymmetric 1,2-Alkynylation☆ Catalytic Asymmetric 1,2-Alkynylation☆ Reference Module in Chemistry, Molecular Sciences and Chemical Engineering Reference Module in Chemistry, Molecular Sciences and Chemical Engineering Reference Module in Chemistry, Molecular Sciences and Chemical Engineering 2015 Refereed Disclose to all
Morimoto H, Fujiwara R, Shimizu Y, Morisaki K, Ohshima T. Morimoto H, Fujiwara R, Shimizu Y, Morisaki K, Ohshima T. Morimoto H, Fujiwara R, Shimizu Y, Morisaki K, Ohshima T. Lanthanum(III) triflate catalyzed direct amidation of esters Lanthanum(III) triflate catalyzed direct amidation of esters Lanthanum(III) triflate catalyzed direct amidation of esters Organic Letters, 16, 7, 2018-2021 Organic Letters, 16, 7, 2018-2021 Organic Letters, 16, 7, 2018-2021 2014 Refereed Disclose to all
Morisaki K, Sawa M, Nomaguchi J.-Y, Morimoto H, Takeuchi Y, Mashima K, Ohshima T. Morisaki K, Sawa M, Nomaguchi J.-Y, Morimoto H, Takeuchi Y, Mashima K, Ohshima T. Morisaki K, Sawa M, Nomaguchi J.-Y, Morimoto H, Takeuchi Y, Mashima K, Ohshima T. Rh-catalyzed direct enantioselective alkynylation of α-ketiminoesters Rh-catalyzed direct enantioselective alkynylation of α-ketiminoesters Rh-catalyzed direct enantioselective alkynylation of α-ketiminoesters Chemistry - A European Journal, 19, 26, 8417-8420 Chemistry - A European Journal, 19, 26, 8417-8420 Chemistry - A European Journal, 19, 26, 8417-8420 2013 Refereed Disclose to all

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Title language:
Conference Activities & Talks
Title Title(Japanese) Title(English) Conference Conference(Japanese) Conference(English) Promotor Promotor(Japanese) Promotor(English) Date Language Assortment Disclose
Remote Asymmetric Induction by Chemoselective C–H Amination Remote Asymmetric Induction by Chemoselective C–H Amination Remote Asymmetric Induction by Chemoselective C–H Amination 11th Seoul-Kyoto-Osaka Joint Symposium on Pharmaceutical Sciences for young Scientists 11th Seoul-Kyoto-Osaka Joint Symposium on Pharmaceutical Sciences for young Scientists 11th Seoul-Kyoto-Osaka Joint Symposium on Pharmaceutical Sciences for young Scientists 2019/06/12 English Disclose to all
触媒的化学選択的C(sp2)–H結合アミノ化による 遠隔位不斉誘導 触媒的化学選択的C(sp2)–H結合アミノ化による 遠隔位不斉誘導 第17回 次世代を担う有機化学シンポジウム 第17回 次世代を担う有機化学シンポジウム 2019/05/31 Japanese Disclose to all
触媒的化学選択的C(sp2)–H結合アミノ化による遠隔位不斉誘導 触媒的化学選択的C(sp2)–H結合アミノ化による遠隔位不斉誘導 第139回薬学会年会 第139回薬学会年会 2019/03/23 Japanese Disclose to all
ロジウム触媒を用いたC(sp2)-Hアミノ化による遠隔位不斉非対称化 ロジウム触媒を用いたC(sp2)-Hアミノ化による遠隔位不斉非対称化 第68回日本薬学会近畿支部総会・大会 第68回日本薬学会近畿支部総会・大会 2018/10/13 Japanese Disclose to all
N無保護トリフルオロメチルケチミンに対する直接的触媒的アルキニル化反応 N無保護トリフルオロメチルケチミンに対する直接的触媒的アルキニル化反応 第137回薬学会年会 第137回薬学会年会 2017 Disclose to all
亜鉛触媒を用いたN無保護トリフルオロメチルケトイミンに対する直接的アルキニル化反応 亜鉛触媒を用いたN無保護トリフルオロメチルケトイミンに対する直接的アルキニル化反応 第63回有機金属化学討論会 第63回有機金属化学討論会 2016 Disclose to all
Development and Mechanistic Studies of Rh-Catalyzed Direct Enantioselective Alkynylation of α-Ketiminoesters Development and Mechanistic Studies of Rh-Catalyzed Direct Enantioselective Alkynylation of α-Ketiminoesters the 252nd ACS National Meeting in Philadelphia the 252nd ACS National Meeting in Philadelphia 2016 Disclose to all
Direct Catalytic Enantioselective Alkynylation of Ketimines Direct Catalytic Enantioselective Alkynylation of Ketimines 5th Junior International Symposium of Cutting-Edge of Organic Chemistry Asia 5th Junior International Symposium of Cutting-Edge of Organic Chemistry Asia 2015 Disclose to all
ロジウム触媒を用いたα-ケチミノエステルに対する直接的触媒的不斉アルキニル化反応の開発 ロジウム触媒を用いたα-ケチミノエステルに対する直接的触媒的不斉アルキニル化反応の開発 第13回次世代シンポジウム 第13回次世代シンポジウム 2015 Disclose to all
ケチミンに対する直接的触媒的不斉アルキニル化反応の開発 ケチミンに対する直接的触媒的不斉アルキニル化反応の開発 第31回有機合成化学セミナー 第31回有機合成化学セミナー 2014 Disclose to all
Rh(III)/Phebox-Catalyzed Direct Enantioselective Alkynylation of α-Ketiminoesters Rh(III)/Phebox-Catalyzed Direct Enantioselective Alkynylation of α-Ketiminoesters XXVI International Conference on Organometallic Chemistry (ICOMC 2014) XXVI International Conference on Organometallic Chemistry (ICOMC 2014) 2014 Disclose to all
ロジウム触媒によるα-ケチミノエステルに対する直接的触媒的不斉アルキニル化反応の開発及びメカニズム解析 ロジウム触媒によるα-ケチミノエステルに対する直接的触媒的不斉アルキニル化反応の開発及びメカニズム解析 第105回有機合成シンポジウム【春】 第105回有機合成シンポジウム【春】 2014 Disclose to all
α-ケト及びケチミノエステルに対する直接的触媒的不斉アルキニル化反応の反応機構解析 α-ケト及びケチミノエステルに対する直接的触媒的不斉アルキニル化反応の反応機構解析 第134回薬学会年会 第134回薬学会年会 2014 Disclose to all
ロジウム触媒によるα-ケトイミノエステルの直接的不斉アルキニル化反応の開発 ロジウム触媒によるα-ケトイミノエステルの直接的不斉アルキニル化反応の開発 第22回福岡万有シンポジウム 第22回福岡万有シンポジウム 2013 Disclose to all
Rh-Catalysed Direct Enantioselective Alkynylation of α-Ketiminoesters Rh-Catalysed Direct Enantioselective Alkynylation of α-Ketiminoesters Twenty-third French-Japanese Symposium on Medicinal and Fine Chemistry Twenty-third French-Japanese Symposium on Medicinal and Fine Chemistry 2013 Disclose to all
α-ケトイミノエステルの直接的触媒的不斉アルキニル化反応の開発 α-ケトイミノエステルの直接的触媒的不斉アルキニル化反応の開発 第133回薬学会年会 第133回薬学会年会 2013 Disclose to all
ロジウム触媒によるα-ケトイミノエステルの直接的不斉アルキニル化反応 ロジウム触媒によるα-ケトイミノエステルの直接的不斉アルキニル化反応 第29回日本薬学会九州支部大会 第29回日本薬学会九州支部大会 2012 Disclose to all
Rh-Catalyzed Direct Asymmetric Alkynylation of α-Ketoiminoesters Rh-Catalyzed Direct Asymmetric Alkynylation of α-Ketoiminoesters 第59回有機金属化学討論会 第59回有機金属化学討論会 2012 Disclose to all
ロジウム触媒によるα-ケトイミノエステルの直接的不斉アルキニル化反応の開発 ロジウム触媒によるα-ケトイミノエステルの直接的不斉アルキニル化反応の開発 第29回有機合成化学セミナー 第29回有機合成化学セミナー 2012 Disclose to all
ロジウム触媒を用いたα-ケトイミノエステルの直接的触媒的不斉アルキニル化反応の開発 ロジウム触媒を用いたα-ケトイミノエステルの直接的触媒的不斉アルキニル化反応の開発 第49回化学関連支部合同九州支部大会 第49回化学関連支部合同九州支部大会 2012 Disclose to all
Rh-Catalyzed Direct Catalytic Asymmetric Alkynylation of α-Ketoiminoesters Rh-Catalyzed Direct Catalytic Asymmetric Alkynylation of α-Ketoiminoesters Symposium on Molecular Chirality ASIA 2012 Symposium on Molecular Chirality ASIA 2012 2012 Disclose to all

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Title language:
Books etc
Author Author(Japanese) Author(English) Title Title(Japanese) Title(English) Publisher Publisher(Japanese) Publisher(English) Publication date Language Type Disclose
Morisaki, K.; Morimoto, H.; Ohshima, T 森﨑 一宏、森本浩之、大嶋孝志 Morisaki, K.; Morimoto, H.; Ohshima, T Reference Module in Chemistry, Molecular Sciences and Chemical Engineering Reference Module in Chemistry, Molecular Sciences and Chemical Engineering Reference Module in Chemistry, Molecular Sciences and Chemical Engineering Elsevier Inc. Elsevier Inc. Elsevier Inc. Joint Work Disclose to all
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Awards
Title(Japanese) Title(English) Organization name(Japanese) Organization name(English) Date
第35回 井上研究奨励賞 35th Inoue Research Award for Young Scientists 井上科学振興財団 Inoue Foundation for Science 2019/02/04
第137回　薬学会年会　優秀発表賞 日本薬学会 2017/03/28
5th Junior International Conference of Cutting-Edge of Organic Chemistry Asia Outstanding Oral Presentation Award Asian Core Program 2015/11/01
第31回有機合成化学セミナー　ポスター賞 有機合成化学協会 2014/09/17
九州大学学生表彰(学術研究表彰) 九州大学 2014/03/27
External funds: competitive funds and Grants-in-Aid for Scientific Research (Kakenhi)
Type Position Title(Japanese) Title(English) Period
若手 Representative 位置選択的C-H結合官能基化 Site-selective C-H bond functionalization 2019/04/01-2022/03/31
特別研究員奨励費 Representative 化学選択性の逆転を指向した触媒反応の開発 2017/04/26-2018/03/31
特別研究員奨励費 Representative 不斉四置換炭素含有アミン類の立体選択的合成 2014/04/25-2017/03/31
Teaching subject(s)
Name(Japanese) Name(English) Term Department Period
基盤精密有機合成化学実習 Laboratory Practice in Basic Fine Organic Synthesis 通年不定 薬学研究科 2019/04-2020/03
基盤精密有機合成化学実験 Research in Basic Fine Organic Synthesis 通年不定 薬学研究科 2019/04-2020/03
基盤精密有機合成化学演習 Basic Organic Chemistry Seminar 通年不定 薬学研究科 2019/04-2020/03
基礎化学実験 Fundamental Chemical Experiments 後期 全学共通科目 2019/04-2020/03

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